Synthesis of Large C–S–N Heterocycles from [Cp2TiS7NR] and Aromatic Bis-Sulfenyl Chlorides (R = H,Me)

The three isomeric benzene bis-sulfenyl chlorides C₆H₄(SC1)₂ react with [C_p2TiS₇NR] (R = H, Me) to give large sulfur-rich heterocycles C₆H₄S₉NR.     

Three-dimensional nitrogen-doped graphene hydrogel supported Co-CeOx nanoclusters as efficient catalysts for hydrogen generation from hydrolysis of ammonia borane

Benefit from the strong synergistic electronic effect between Co and CeO_x, as well as the strong metalsupport interaction between Co-CeO_x and 3D NGH, the as-synthesized Co-(CeO_x)_0.91/NGH catalyst exhibits excellent catalytic activity toward hydrolysis of ammonia borane, with the turnover frequency (TOF) value of 79.5 min^-1.     

Synthesis and Application of Some Dianilinosilanes,Bis (Trimethylsilyl) Phenylenediamines and Dialkyl Benzo-1,3,2-Diazasilolines as Antioxidants

Negative hyperconjugation of the type n_N→σ* is responsible for the planar or almost planar geometry at nitrogen in certain S–N compounds.     

Malonyl peroxides in organic synthesis (microreview)

Chemistry of Heterocyclic Compounds - A summary of the most recent applications of malonyl peroxides as reagents in organic synthesis is discussed. The microreview covers the latest selected...     

Frontoparietal activity with minimal decision and control in the awake macaque at 7 T

Previous imaging work has identified a frontoparietal network in the human brain involved in many different cognitive functions, as well as in simple updates of attended information. To determine whether a similar network is present in the monkey brain and direct future electrophysiological recordings, we examined the activation of frontoparietal areas during visual stimulation in the awake, fixating monkey. We measured activity with BOLD fMRI in three animals and analyzed the data individually for each animal and at group level. We found reliable activations in lateral prefrontal and parietal areas, even though task-related decision making was minimal, as a response to simple update of visual information. These activations were significant for each individual animal, as well as at group level. Similar to human imaging results the update of visual input was enough to activate an extensive network of frontoparietal cortex in the macaque brain, a network which is normally associated with complex cognitive control processes.